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This page was last updated April 2008.

Recent news of sustainable chemistry issues and industrial developments.

Envision Chemistry/Peter Fisk Associates scientists have recently had a paper published on the subject of the principles of design of chemicals with low environmental hazards. This paper provides a broad summary of the issues and advantages relating to the development of environmentally-benign chemicals, from the design stage; describes issues and objectives in the context of specific chemical properties, and sets out some approaches that can help. This paper was one of several published in a green chemistry special supplement (see full reference below):

Fisk, Peter R. and Wildey, Rosalind J. (2008). Principles of design of chemicals with low environmental hazard. Supplement to Chimica Oggi/Chemistry Today, 25 (6): Green Chemistry/Ionic liquids, pp 3-6.

Please select from the following list:

SUSTAINABLE CHEMISTRY

INDUSTRIAL INNOVATION

REGULATORY NEWS

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SUSTAINABLE CHEMISTRY

SusChem newsletter
Added February 2008

The 8th edition of the SusChem newsletter is available from http://www.suschem.org. As well as developments in the area of promoting a sustainable chemistry industry, the newsletter also includes details of the SusChem stakeholder workshop held in Berlin at the end of January 2008.

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Household chemicals and substitution
Added April 2007

A report has been published by an NGO on substitution of toxic chemicals in household products. This report reviews progress that has been made in by companies in substitution of hazardous substances. It indicates that substitution can be done where the will to do so exists, but legislation may be required to encourage more reluctant manufacturers to take substitution seriously. The report can be accessed by clicking here.

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SusChem work preparation
Added April 2007

SusChem, the European technology platform for Sustainable Chemistry, has published its Implementation Action Plan, available from its website. As well as research objectives, outlined in the context of eight key themes, its innovation objectives include the establishment of infrastructure for knowledge share, stakeholder dialogue, education and SME support.

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INDUSTRIAL INNOVATION

2007 Presidential Green Chemistry Award
Added February 2008

The projects that have received the 2007 Presidential Green Chemistry Award give an indication of the diversity of areas in which innovation can lead to more sustainable chemistry.

They include:

  • A soya based adhesive for plywood, as an alternative to formaldehyde based adhesives.
       
  • An advanced metal catalyst for the production of hydrogen peroxide from hydrogen and oxygen.
       
  • Vegetable-based polyols for use in polyurethane synthesis.
       
  • A technique for the elimination of by-products and waste from hydrogenation reactions.

    For more information see: http://www.epa.gov/greenchemistry/pubs/pgcc/past.html

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    Constructing Alternative Chemicals
    As described elsewhere in this website, an important strategy in creating a sustainable chemical industry is in the development of safer chemicals. Some examples of new ‘greener’ technological developments in the chemicals industry, publicised by the relevant companies and described in Chemistry and Industry journal (Issue No 21 - Page 19 ) follow (please note that Envision Chemistry was not involved with development of these new technologies).

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    Substituting greener chemicals
    Substitution of hazardous substances with safer alternatives can significantly reduce the impact of the chemical industry on the environment and human health. Sometimes regulatory action is needed to stimulate the development of alternatives. An example of this is the proposal by DEFRA to phase out a substance used in non-stick coatings. Perfluorooctane sulphonate (PFOS) was widely used in non-stick coatings until the major manufacture voluntarily withdrew PFOS-related compounds. In June 2004, prompted by growing evidence that PFOS is toxic and persistent, and accumulates in human blood, Alun Michael, the environment minister announced the intention of the UK government to ban PFOS compounds unilaterally. DEFRA published a risk reduction strategy in August 2004.

    It is important that substitutes for PFOS (in fire fighting foams, for example) are properly assessed to make sure that they really are safer. There is still a need to develop alternatives for some of the current applications (semiconductors, photography and aviation). Property prediction can be very helpful in the development of alternatives, as it can be used to assess the likely environmental impact of an alternative before it has been synthesized, potentially saving a great deal of time and money.

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    Taking the initiative
    Adapted from "Green initiative" Chemisty & Industry 4 April 2005

    Both cleaner processing techniques and greener materials are available today to assist in the transformation of the chemical industry that is needed to improve its image with the public, as well as to comply with increasingly stringent environmental legislation. There can be significant economic advantages to adopting green chemical technologies, as well as the improvement to competitiveness resulting from a reputation for environmental integrity.

    Cleaner processing techniques include:

  • Process intensification using small-scale micro-reactors which maximise mass and heat transfer and catalytic efficiencies. They also improve product consistency and reduce waste
       
  • Real time control: accurate measurement and control of chemical processes reduces energy and feedstock consumption
       
  • Process modelling: simulating effects of process changes on efficiency can enable real time control to be even more effective in improving efficiency and reducing environmental impact
       
  • Alternative energy sources such as microwaves and radio frequency heating enable heating to be more carefully directed and controlled. Side reactions are reduced and reaction efficiency increased
       
  • Alternative energy sources such as microwaves and radio frequency heating enable heating to be more carefully directed and controlled. Side reactions are reduced and reaction efficiency increased
       
    Greener Materials
       
  • Substitution of chemicals with less hazardous alternatives
       
  • Use of modelling to predict properties and assess environmental impact of proposed alternatives
       
  • Removal of reaction products by selective membranes in equilibrium limited reactions improving conversion yields
       
  • Integrating catalyst with membrane in such reactions, further boosting yields
       
  • Nano-particle technology can be used to improve functionality eg of metal catalysts, industrial coatings
       
  • Use of closed loop systems to recycle used solvent in small volume and batch manufacturing systems, not just in large-scale plants
       
  • Replacement of organic solvents e.g. by supercritical carbon dioxide.

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    REGULATORY NEWS

    REACH is now in force
    Added July 2007

    The REACH Regulation became law in December 2006 and came into force on June 1st 2007. It is intended that the registration, evaluation and authorisation procedures will ultimately lead to control of chemical risks to health and the environment in Europe, and promote the substitution of more hazardous substances with substances which are of less concern. The European Chemicals Agency is now operational. It will be responsible for managing the registration, evaluation, authorisation and restriction processes for chemical substances.

    Sources of information include:

  • The UK Government REACH website
  • The European Chemicals Agency website
  • The European Union REACH website

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    WEEE now in force in UK
    Added July 2007

    The long-awaited Waste Electrical and Electronic Equipment regulations came into force on 1st July 2007. These Regulations implement EC Directives 2002/96/EC and 2003/108/EC which aim to minimise the impact of electrical and electronic goods on the environment. They make producers responsible for financing the collection, treatment, and recovery of waste electrical equipment. Distributors are obliged to allow consumers to return their waste equipment free of charge.

    For more information see http://www.dti.gov.uk/innovation/sustainability/weee/page30269.html

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    Proposal for changes to classification, labelling and chemicals
    Added July 2007

    A proposal has been put forward to the EU system of classification of chemical substances and mixtures to the United Nations Globally Harmonised System (GHS). New EU legislation will replace the current law on the classification, labelling and packaging of chemical substances (Directive 67/548/EEC) and mixtures (Directive 1999/45/EC). The new legislation will integrate GHS into EU law, and will complement the REACH Regulation. The proposed Regulation will be discussed in the European Council and Parliament. After it has entered into force the deadlines for substance reclassification of substances and mixtures will be 1 December 2010 and 1 June 2015 respectively.

    For more information see http://ec.europa.eu/enterprise/reach/ghs_en.htm

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    Photography courtesy of Steve Graham, US Fish and Wildlife Service

     

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